It seems that the bug which was reported 3 years ago (["#tilde" little bug in ROOT version 5.34.00? is now observed on the opposite side with root version 6.03/03 for #tilde on .png files :
Mac has 2 to graphics backend now. X11 and Cocoa. Cocoa Is now the default. I think you are using that one ? (when root start you should not see the X11 icon on the dock).
Yes you can still install the X11 version of course bu the default one is Cocoa. I am now looking at this to fix it. Thanks to have seen it. By the way if you run root in batch the png is correct.